Preheat oven to 350°F/180°C. Line a 9×9 pan with alumium foil. Grease if desired.
Sift together flour and cocoa into bowl.
In small pan, melt butter over med-low heat. Continue stirring as it hisses and pops until it is golden yellow and silent.
Remove from heat and stir in dark chocolate.
In a large bowl, combine granulated sugar, brown sugar, salt, eggs, vanilla, and instant espresso in bowl. Whip until fluffy, about 8 minutes.
Mix in dark chocolate/butter mixture. After that's combined, add cocoa/flour mixture and incorporate into batter.
Pour into pan. Bake ~30 minutes. Time is based on a light aluminum pan. Glass will take longer (~45 minutes). Internal temperature should be 205°F/95°C.